Do not try to hold your breath. Same problem as a SCUBA diver trying to ascend while holding their breath. As the air expands because of the lower pressure it can cause an air embolism. This basically means your lungs expand too far and you rupture a lung.
You would also start to suffer some of the issues a SCUBA diver suffers from surfacing too fast unrelated to lungs. In general, this is called decompression sickness. The short version is rapid depressurization causes formation of bubbles of inert gases in your tissues. Nitrogen is a common culprit. The problem is the bubbles can form or migrate almost anywhere. Most common places are large joints (e.g., elbows, hips, knees, and shoulders) causing joint pain. This is the bends. Other places include the ears (e.g., vertigo, nausea, and vomiting), brain (e.g., amnesia and seizures), skin (e.g., itching and edema), etc. So rapid depressurization can be a big issue.
Freezing would not be an issue. Space is cold, but not cold enough for it to matter. You are going to run out of sufficient oxygen in your blood to keep your brain alive before you freeze. On which note, once you stop breathing and you're not holding your breath, it takes about 15 - 20 sec for your blood to run out of sufficient oxygen to keep you conscious.
You would also get a sunburn from unfiltered UV radiation.
In general, I imagine you could be naked in space for a good 30 sec and come out of it with nothing more major than the bends and a bad sunburn. That is recoverable in about a week.
The idea of blood boiling needs some explaining. At very low pressures liquids boil because the vapor pressure exceeds the ambient pressure. Vapor pressure increases with temperature. So, high temperatures also make liquids boil. You can find the vapor pressure curve with the relationship between pressure and temperature using Google. Anyway, the reason this does not matter is your blood is never exposed to vacuum. Your circulatory system is pressurized and stays that way until you lose lots of blood. Thus, explaining the danger of losing lots of blood to injuries. Basically, your blood pressure drops too low to carry sufficient oxygen to your brain quickly enough. The common trauma response is to correct the circulatory pressure issue using saline solution, blood transfusions, etc. Granted, liquid exposed to vacuum would boil. So, saliva as your nasal passage and eustachian tubes cannot be closed. Maybe sweat? Possibly the liquid coating your eyes? So, keep your eyes squeezed shut or suffer the world's worst case of dry eye
There is no pressure that would cause us to explode. You can put someone at 0.001 ATM and they will just suffer the decompression sickness symptoms faster and have a better chance of badly injuring their lungs. There is also no dying instantly. You will be conscious for about 15 - 30 sec depending on how fast you depressurized and stopped absorbing oxygen into your blood. Even unconscious, you would be alive for a good min or two as your brain burned through your body's oxygen.
Gravity was reasonably accurate. Dead from hypoxia. Boiling of surface liquids like saliva. Bad edema of the skin from acute decompression sickness. Slightly frosty from the low temperature and a good 15 - 20 min of floating in space.